|
|
3-hydroxypimeloyl-CoA + NAD+ <=> H+ + NADH + 3-oxopimeloyl-CoA
|
1.1.1.259
3-hydroxypimeloyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
|
BRENDA:
BR22610
KEGG:
R05305
MetaCyc:
1.1.1.259-RXN
|
|
|
|
6-carboxyhex-2-enoyl-CoA + H2O <=> 3-hydroxypimeloyl-CoA
|
4.2.1
|
–
|
|
KEGG:
R05601
MetaCyc:
RXN-8031
|
|
|
|
pimeloyl-CoA + NAD+ <=> H+ + NADH + 6-carboxyhex-2-enoyl-CoA
|
1.3.1.62
pimeloyl-CoA dehydrogenase
|
–
|
|
BRENDA:
BR29441
KEGG:
R05311
MetaCyc:
1.3.1.62-RXN
|
|
|
|
3-oxopimeloyl-CoA + CoA <=> glutaryl-CoA + acetyl-CoA
|
2.3.1
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
–
|
|
KEGG:
R05586
MetaCyc:
RXN-8032
|
|
|
|
2-ketocyclohexane-1-carboxyl-CoA + H2O <=> H+ + pimeloyl-CoA
|
3.1.2
3.7.1
|
–
–
|
|
KEGG:
R05592
MetaCyc:
R268-RXN
|
|
|
|
cyclohex-1-ene-1-carbonyl-CoA + oxidized_electron_transfer_flavoprotein + H+ <=> cyclohexa-1,5-diene-1-carbonyl-CoA + reduced_flavodoxin
|
1.3.8.10
cyclohex-1-ene-1-carbonyl-CoA dehydrogenase
|
–
|
|
MetaCyc:
R265-RXN
|
|
|
|
cyclohex-1-ene-1-carbonyl-CoA + H2O <=> 2-hydroxycyclohexane-1-carbonyl-CoA
|
4.2.1
4.2.1.100
cyclohexa-1,5-dienecarbonyl-CoA hydratase
|
–
–
|
|
BRENDA:
BS186637
KEGG:
R05600
MetaCyc:
R266-RXN
|
|
|
|
2-hydroxycyclohexane-1-carbonyl-CoA + NAD+ <=> H+ + 2-ketocyclohexane-1-carboxyl-CoA + NADH
|
1.1.1
|
–
|
|
KEGG:
R05582
MetaCyc:
R267-RXN
|
|
|
|
cyclohexa-1,5-diene-1-carbonyl-CoA + oxidized_ferredoxin + ADP + phosphate <=> benzoyl-CoA + reduced_ferredoxin_[iron-sulfur]_cluster + ATP + H2O
|
1.3.7.8
benzoyl-CoA reductase
|
–
|
|
BRENDA:
BR1225
KEGG:
R02451
MetaCyc:
1.3.99.15-RXN
|
|